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GCSE/Combined Science/WJEC

C3.2Covalent bonding: simple molecules, dot-and-cross diagrams; properties

Notes

Covalent bonding

A covalent bond forms when two non-metal atoms share a pair of electrons. Each atom achieves a stable noble-gas outer shell (usually 8, or 2 for hydrogen and helium).

Simple molecules

Common GCSE examples:

MoleculeFormulaBonds
HydrogenH_21 single
Hydrogen chlorideHCl1 single
WaterH_2O2 single
MethaneCH_44 single
AmmoniaNH_33 single
OxygenO_21 double
NitrogenN_21 triple
Carbon dioxideCO_22 double

A double bond shares two pairs (4 electrons); a triple bond shares three pairs.

Dot-and-cross diagrams

Show outer-shell electrons only. Use one symbol (dot) for one atom and another (cross) for the other so you can see what each atom contributes. Only the shared pairs sit in the overlap of the two atomic shells.

Properties of simple molecular substances

  • Low melting and boiling points — weak intermolecular forces between molecules need only a little energy to overcome (the strong covalent bonds inside the molecule are NOT broken on melting or boiling).
  • Do not conduct electricity — molecules are neutral; no free ions or electrons.
  • Many are gases or liquids at room temperature.

WJEC exam tip

When asked why methane has a low boiling point, do not say "the covalent bonds are weak". They are strong. The answer is: weak intermolecular forces between separate methane molecules need only a little energy to overcome. Always specify "between molecules".

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Practice questions

Try each before peeking at the worked solution.

  1. Question 15 marks

    Bonding in water

    WJEC Unit 1 Chemistry — Foundation tier

    (a) Describe how a covalent bond forms between hydrogen and oxygen in a water molecule. (3 marks)
    (b) State the formula and the number of single covalent bonds in a water molecule. (2 marks)

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  2. Question 24 marks

    Properties of CO_2

    WJEC Unit 1 Chemistry — Higher tier

    CO_2 is a gas at room temperature and does not conduct electricity.

    Explain these two properties using ideas about bonding. (4 marks)

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  3. Question 35 marks

    Dot-and-cross for methane

    WJEC Unit 1 Chemistry — Higher tier

    Methane (CH_4) is a simple covalent molecule.

    (a) Describe what is shown in a dot-and-cross diagram of methane. (3 marks)
    (b) Explain why methane has a low boiling point even though the C-H bonds are strong. (2 marks)

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Flashcards

C3.2 — Covalent bonding: simple molecules, dot-and-cross diagrams; properties

7-card SR deck for WJEC GCSE Combined Science (Double Award) — Leaves Batch 2 topic C3.2

7 cards · spaced repetition (SM-2)